Clara Oswald had an iPhone. (TV: The Time of the Doctor, et al.) During the Twelfth Doctor's imprisonment in the Prison, Clara's iPhone was incinerated. (PROSE: The Blood Cell) Clara obtained another and, in her form, Bonnie used the phone to record video and send and receive video calls, while Clara, connected to Bonnie's mind, sent text messages to the Twelfth Doctor without Bonnie realising. (TV: The Zygon Inversion)
The members of the Coal Hill Year 8 Gifted and Talented Group all had iPhones. In the 21st century, when Earth had become overrun with trees, they used Samson's to take selfies. (TV: In the Forest of the Night)
Courtney Woods had an iPhone as well, and she used it to post pictures of the Twelfth Doctor on the Moon onto Tumblr in the year 2049. Clara Oswald noted that to the Doctor. Even though he said she couldn't just put pictures of him online he was later able to use the online pictures via her phone to lead her back to him in the TARDIS. (TV: Kill the Moon)
In 1955, Graham O'Brien fakes his identity as "Steve Jobs" and claims to be developing a telephone capable of playing music, taking photographs, sending letters, and serving as a calendar. This describes many of the iPhone's varied functions.