Hmm… Tennant is pretty hard, but I have a few for Capaldi. Flatline and Time Heist are my two favorite episodes of all time, and Heaven Sent is of course a classic.
For Tennant, I’m sure most people can appreciate The Waters of Mars, although that is when 10 slowly starts to spiral. Silence in the Library/Forest of the Dead is spectacular, especially after seeing River’s plot unfold during the Smith era. And Blink is pretty good, but in my opinion it best on a first watch.