The War Chief

The War Chief, known in the Time Lord Academy as Magnus, was a former friend of The Doctor and, later, a renegade Time Lord who assisted the War Lords. After the failure of the War Lords, he regenerated, although he was deformed by the experience. He then travelled back in time, in order to use the Nazis as his agents. He was finally stopped by the Seventh Doctor, and hasn't appeared since.

Life on Gallifrey
Once called Magnus, he in those days belonged to the same clique as the Doctor, who as youths called themselves the Deca. (PDA: Divided Loyalties). A holo-simulation shown by the Doctor to Bernice Summerfield detailed the later days of their relationship. According to the simulation, Magnus grew into an ambitious and arrogant Time Lord who already had little time for "Theet". Magnus engaged himself in a scheme to provide Gallifrey with a new power source derived from a sphere of artron energy and, in so doing, re-vitalize the decadent Gallifreyan culture. The Doctor made himself an unwelcome guest observer of the experiment. He realised the sphere was in fact a living being and that Magnus' actions were killing it. The Doctor sabotaged Magnus' equipment and freed the creature, an act for which the Time Lords commended him. This angered Magnus even more. He and Magnus were bitter enemies from that day on. (DWM: Flashback)

Ally of the War Lords
Now calling himself the War Chief, he assisted the War Lords, who had abducted soldiers from wars spread across Earth's history to play in simulated versions of the wars from which they originated. Thinking Humans the most vicious species in the galaxy, the aliens hoped to later pit the survivors against each other and to use the humans to conquer Mutter's Spiral. The War Chief aided the War Lords by giving them technology to build basic TARDIS-like space-time machines, SIDRATs, which they used to kidnap the human soldiers and travel between era-specific zones which they had created. The War Chief and the Doctor met and recognised each other. The War Chief solicited the Doctor's help to double-cross the War Lords and seize power for themselves. The Doctor pretended to accept the War Chief's offer. (DW: The War Games)

At the same time, the Security Chief of the operation distrusted the War Chief, believing he meant to call in the Time Lords. The two engaged in a series of machinations against each other which ended with the War Chief disgraced, though he shot his rival dead. Unable to resolve matters and return the soldiers to their own times, the Doctor summoned the Time Lords for aid, while the War Lords discovered the War Chief's plans and executed him. (DW: The War Games) Unknown at the time, the War Chief did not die but, rather, underwent a faulty regeneration. His new form appeared like two bodies fused together. He took to wearing cloaks and hoods to disguise the fact. (NA: Timewyrm: Exodus)

Aftermath
Hiding his misshapen doubled body in cloaks and hoods, the War Chief served as an occult advisor to Adolf Hitler under the name "Doktor Felix Kriegslieter" in hopes of changing history by using the Nazis as his agents. The Doctor confronted him once more at this time, prompting the War Chief to try and take possession of the Doctor's healthy body and his remaining six regenerations. However, his attempts to replace Hitler with Heinrich Himmler were thwarted by Himmler's devotion to his Führer (as opposed to other Nazi officers who merely served Hitler out of necessity), allowing the Doctor to alert Hermann Goering to "Kriegslieter's" betrayal and destroy the War Chief's base by overloading its nuclear reactors, his agents being killed by the Nazis due to their lack of initiative. (NA: Timewyrm: Exodus)

Personality
The War Chief was an ambitious and arrogant individual, with a degree of cunning, and great tactical abilities. He pretended to loyally serve the War Lords, while at the same time plotting to take control of them. The War Chief was unconcerned about using up regenerations, and never listened to the Doctor, who advised him not to waste them. Behind the War Chief's actions lay real idealism, tainted with powerlust. (MA: Invasion of the Cat-People)

Behind the scenes

 * FASA's The Doctor Who Role Playing Game identified the War Chief, the Monk and the Master as different incarnations of the same renegade Time Lord. However in the module Legions of Death he appears as a Renegade Time Lord who has been a former ally of The Master. In addition, the non-canon novel Time's Champion indicates that the War Chief is in fact an early incarnation of the Master. Canon comics and original novels have since contradicted this. Though this is rendered somewhat moot due to all spin-off material being of uncertain canonicity. Also, it would be possible that the Doctor is meeting the Master in his own past.